When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | Cl2_JPL-2010(2011)_298K_260-550nm(rec).txt |
NAME: | chlorine |
FORMULA: | Cl2 |
AUTHOR(YEAR): | JPL-2010(2011) |
T: | 298K |
λ: | 260-550nm(rec) |
BIBLIOGRAPHY: |
S.P. Sander, J. Abbatt, J. R. Barker, J. B. Burkholder, R. R. Friedl, D. M. Golden, R. E. Huie, C. E. Kolb, M. J. Kurylo, G. K. Moortgat, V. L. Orkin and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 17",
JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, 2011; http://jpldataeval.jpl.nasa.gov/
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COMMENTS: | JPL-2010 recommendation, adopting the earlier recommendation of
S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, G.K. Moortgat, H. Keller-Rudek, P.H. Wine, A.R. Ravishankara, C.E. Kolb, M.J. Molina, B.J. Finlayson-Pitts, R.E. Huie, V.L. Orkin, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15“, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006; http://jpldataeval.jpl.nasa.gov/ :
Absorption cross sections calculated at 5-nm intervals using the semiempirical function (eqn. 12) σ(λ,T) = 2.73×10-19 cm2 × tanh0.5 × exp{-99.0 × tanh × [ln(329.5 nm/λ)]2}
+ 9.32×10-21 cm2 × tanh0.5 × exp{-91.5 × tanh × [ln(406.5 nm/λ)]2} with tanh = tanh(hc×559.751 cm-1/2KT) = tanh(402.7/T); λ in nm, 250 < λ < 550 nm, and T in K; 300 K > T > 195 K, derived by D. Maric, J.P. Burrows, and G.K. Moortgat, "A study of the UV-visible absorption spectra of Br2 and BrCl," J. Photochem. Photobiol. A: Chem. 70, 205-214 (1993);DOI: 10.1016/1010-6030(93)85045-A |
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